Shorthand notation for Glycerolipids (GL)

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(New page: *Shorthand notation: Lipid class abbreviation followed by number of C-atoms:number of double bonds. *Fatty acids linked to the glycerol are known: **'''separator _: sn-position of the fa...)
Current revision (16:31, 29 October 2015) (view source)
 
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= Rules for the annotation  =
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*Shorthand notation: Lipid class abbreviation followed by number of C-atoms:number of double bonds.  
*Shorthand notation: Lipid class abbreviation followed by number of C-atoms:number of double bonds.  
*Fatty acids linked to the glycerol are known:  
*Fatty acids linked to the glycerol are known:  
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**'''P = proven O-alk-1-enyl-bond''' (acid-sensitive ether bond in “plasmalogens”).  
**'''P = proven O-alk-1-enyl-bond''' (acid-sensitive ether bond in “plasmalogens”).  
*More than one "non"-ester bond is indicated in front of the bond type as d for di, t for tri.
*More than one "non"-ester bond is indicated in front of the bond type as d for di, t for tri.
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= Lipid class abbreviations  =
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*Monoglycerides - MG
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*Diglycerides - DG
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*Triglycerides - TG
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= Examples  =
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{| class="wikitable" style="text-align: center"
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|-
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! scope="col" | Bond type<br>
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! scope="col" | Lipid class level mass$<br>
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! scope="col" | Lipid species level§<br>
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! scope="col" | Bond type level<br>
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! scope="col" | Fatty acyl/alkyl level<br>
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! scope="col" | Fatty acyl/alkyl position level<br>
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! scope="col" | LIPID MAPS Fatty acyl/alkyl structure level<br>
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|-
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| Acyl <br>
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| MG (358)<br>
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| MG 18:0 <br>
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| MG 18:0 <br>
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| MG 18:0 <br>
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| MG 0:0/18:0/0:0 <br>
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| <br>
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|-
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| Alkyl <br>
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| MG (344)<br>
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| MG O-18:0<br>
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| MG O-18:0 <br>
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| MG O-18:0 <br>
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| MG 0:0/O-18:0/0:0 <br>
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| <br>
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|-
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| Diacyl <br>
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| DG (594)<br>
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| DG 34:1 <br>
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| DG 34:1 <br>
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| DG 16:0_18:1 <br>
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| DG 16:0/18:1/0:0<br>
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| DG 16:0/18:1(9Z)/0:0<br>
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|-
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| Alkyl-acyl <br>
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| DG (580)<br>
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| DG O-34:1<br>
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| DG O-34:1 <br>
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| DG O-16:0_18:1 <br>
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| DG O-16:0/18:1/0:0 <br>
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| DG O-16:0/18:1(9Z)/0:0 <br>
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|-
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| Dialkyl <br>
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| DG (538)<br>
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| DG 30:1<br>
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| DG dO-32:1 <br>
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| DG O-16:0_O-16:1 <br>
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| DG O-16:0/O-16:1/0:0 <br>
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| DG O-16:0/O-16:1(9Z)/0:0 <br>
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|-
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| Dialkyl <br>
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| TG (858)<br>
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| TG 52:2 <br>
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| TG 52:2 <br>
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| TG 16:0_18:1_18:1 <br>
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| TG 16:0/18:1/18:1<br>
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| TG 16:0/18:1(9Z)/18:1(11Z)<br>
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|-
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| Alkyl-diacyl <br>
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| TG (844)<br>
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| TG O-52:2<br>
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| TG O-52:2 <br>
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| TG O-16:0_18:1_18:1 <br>
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| TG O-16:0/18:1/18:1 <br>
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| TG O-16:0/18:1(9Z)/18:1(11Z)<br>
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|-
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| Dialkyl-acyl<br>
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| TG (830)<br>
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| TG 50:2<br>
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| TG dO-52:2<br>
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| TG O-18:1_O-16:0_18:1<br>
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| TG O-18:1/O-16:0/18:1<br>
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| TG O-18:1(9Z)/O-16:0/18:1(9Z)<br>
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|-
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| Trialkyl<br>
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| TG (816)<br>
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| TG O-50:2<br>
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| TG tO-52:2<br>
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| TG O-18:1_O-16:0_O-18:1<br>
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| TG O-18:1/O-16:0/O-18:1<br>
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| TG O-18:1(9Z)/O-16:0/O-18:1(9Z)<br>
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|}
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$ m is the uncharged molecular mass<br> § Annotation based on assumption of even numbered carbon chains only
[[Category:Nomenclature]]
[[Category:Nomenclature]]

Current revision

Rules for the annotation

  • Shorthand notation: Lipid class abbreviation followed by number of C-atoms:number of double bonds.
  • Fatty acids linked to the glycerol are known:
    • separator _: sn-position of the fatty acids is not known
    • separator /: sn-position of fatty acids is proven (order sn-1/sn-2/sn-3 for GL; sn-1/sn-2 or sn-2/sn-3 for GP); no FA linked 0:0
  • Other bond types than ester bonds are indicated as follows in front of the sum of C-atoms or fatty acid:
    • O = proven O-alkyl-bond (it is important to note that “O” after the number of carbons designates a keto bond)
    • P = proven O-alk-1-enyl-bond (acid-sensitive ether bond in “plasmalogens”).
  • More than one "non"-ester bond is indicated in front of the bond type as d for di, t for tri.

Lipid class abbreviations

  • Monoglycerides - MG
  • Diglycerides - DG
  • Triglycerides - TG

Examples

Bond type
Lipid class level mass$
Lipid species level§
Bond type level
Fatty acyl/alkyl level
Fatty acyl/alkyl position level
LIPID MAPS Fatty acyl/alkyl structure level
Acyl
MG (358)
MG 18:0
MG 18:0
MG 18:0
MG 0:0/18:0/0:0

Alkyl
MG (344)
MG O-18:0
MG O-18:0
MG O-18:0
MG 0:0/O-18:0/0:0

Diacyl
DG (594)
DG 34:1
DG 34:1
DG 16:0_18:1
DG 16:0/18:1/0:0
DG 16:0/18:1(9Z)/0:0
Alkyl-acyl
DG (580)
DG O-34:1
DG O-34:1
DG O-16:0_18:1
DG O-16:0/18:1/0:0
DG O-16:0/18:1(9Z)/0:0
Dialkyl
DG (538)
DG 30:1
DG dO-32:1
DG O-16:0_O-16:1
DG O-16:0/O-16:1/0:0
DG O-16:0/O-16:1(9Z)/0:0
Dialkyl
TG (858)
TG 52:2
TG 52:2
TG 16:0_18:1_18:1
TG 16:0/18:1/18:1
TG 16:0/18:1(9Z)/18:1(11Z)
Alkyl-diacyl
TG (844)
TG O-52:2
TG O-52:2
TG O-16:0_18:1_18:1
TG O-16:0/18:1/18:1
TG O-16:0/18:1(9Z)/18:1(11Z)
Dialkyl-acyl
TG (830)
TG 50:2
TG dO-52:2
TG O-18:1_O-16:0_18:1
TG O-18:1/O-16:0/18:1
TG O-18:1(9Z)/O-16:0/18:1(9Z)
Trialkyl
TG (816)
TG O-50:2
TG tO-52:2
TG O-18:1_O-16:0_O-18:1
TG O-18:1/O-16:0/O-18:1
TG O-18:1(9Z)/O-16:0/O-18:1(9Z)

$ m is the uncharged molecular mass
§ Annotation based on assumption of even numbered carbon chains only

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